AVS 58th Annual International Symposium and Exhibition
    Graphene and Related Materials Focus Topic Wednesday Sessions
       Session GR-WeA

Invited Paper GR-WeA1
Scanning Probe and Optical Microscopy and Spectroscopy of Graphenes on (sub-) Molecular Layers on Atomically Flat Substrates

Wednesday, November 2, 2011, 2:00 pm, Room 208

Session: Graphene Characterization including Microscopy and Spectroscopy
Presenter: Jürgen Rabe, Humboldt University Berlin, Germany
Authors: J. Rabe, Humboldt University Berlin, Germany
N. Severin, Humboldt University Berlin, Germany
P. Lange, Humboldt University Berlin, Germany
M. Dorn, Humboldt University Berlin, Germany
S. Eilers, Humboldt University Berlin, Germany
Correspondent: Click to Email

Graphenes were used to cover solid substrates, including silicon wafers and atomically flat mica, pre-coated with molecularly thin liquids as well as single macromolecules. Optical reflection microscopy was employed to identify single graphenes on optically transparent substrates in optical reflection microscopy with a contrast of more than 12% [1]. A combined fluorescence and scanning force microscopy study revealed that that graphene is not only a highly conductive and transparent electrode, but also a most effective barrier to protect conjugated polymers against degradation through water and oxygen [2]. Time resolved pump-probe spectroscopy revealed ultrafast nonequilibrium carrier dynamics [3]. Finally, scanning force and electrostatic force microscopy, and also STM/STS were used to characterize structure and electronic properties of single graphenes with molecules either on top or below the graphene, revealing a remarkable stability of the elctronic properties of these hybrid systems.

[1] M. Dorn, P. Lange, A. Chekushin, N. Severin, J.P. Rabe, J. Appl. Phys. 108 (2010) 106101.

[2] P. Lange, M. Dorn, N. Severin, D. Vanden Bout, J.P. Rabe, Verhandlungen DPG Regensburg 2010.

[3] M. Breusing, S. Kuehn, T. Winzer, E. Malic, F. Milde, N. Severin, J.P. Rabe, C. Ropers, A. Knorr, T. Elsaesser, Phys. Rev. B (2011) 153410.