AVS 56th International Symposium & Exhibition
    Thin Film Tuesday Sessions
       Session TF2-TuM

Invited Paper TF2-TuM1
How Surface Reactions Afford Ultra-Conformal CVD: A Zone Diagram and the Application of Suppressor Species

Tuesday, November 10, 2009, 8:00 am, Room B4

Session: ALD/CVD: Basics, Organics, Electronics
Presenter: J.R. Abelson, University of Illinois at Urbana-Champaign
Correspondent: Click to Email

We present a unified description of conformal film growth in recessed features by low-pressure chemical vapor deposition. Experimental data on step coverage and growth rate are interpreted in terms of a Langmuirian kinetic model for the elementary surface processes. This model is combined with the continuity equation for gas transport and consumption to predict the values of precursor pressure and substrate temperature (p,T) that are necessary for conformal coverage to occur for a given precursor. We introduce a conformal zone diagram that considers the gas phase limitations (maximum precursor pressure, onset of secondary reactions), the surface limitations (minimum reaction temperature, precursor adsorption and desorption rates, film growth rate) and the aspect ratio of the feature to be coated; the allowed intersection between the resulting boundaries defines the (p,T) zone for conformal growth. Sufficient precursor pressure is identified as a major requirement for conformal film growth, one that is not met by many commercially available molecules. We show that growth inhibition, the use of a second species to decrease the surface reactivity, can enlarge the conformal zone of low-pressure precursors. We incorporate the inhibition mechanism into the kinetic model; the theoretical predictions are in excellent agreement with experimental results. We also extend the kinetic model to the case of compound film growth from two reactants. Finally, we derive an approximate analytical solution to the inverse problem: what are the experimental conditions necessary to afford a desired degree of step coverage on a given aspect ratio feature at a desired growth rate. The solution depends on a set of rate constants in the kinetic model that can be extracted from measurements of the film growth rate as a function of precursor pressure and substrate temperature on trench or planar substrates.