AVS 56th International Symposium & Exhibition
    Thin Film Thursday Sessions
       Session TF-ThM

Paper TF-ThM9
Synergistic Ag (111) and Cu (111) Texture Evolution in Phase Segregated Cu1-xAgx Magnetron Sputtered Composite Thin Films

Thursday, November 12, 2009, 10:40 am, Room B4

Session: Nanostructuring Thin Films II
Presenter: D.I. Filoti, University of New Hampshire
Authors: D.I. Filoti, University of New Hampshire
A.R. Bedell, University of New Hampshire
J.M.E. Harper, University of New Hampshire
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We investigated the texture and microstructure evolution of Cu1-xAgx composite thin films through x-ray diffraction pole figures as a function of composition for x ≤ 0.5. As-codeposited at room temperature by magnetron sputtering, the fcc composite Cu1-xAgx emerge as a phase-segregated thin film, when the Ag volume fraction represents more than 15 at. % up to 50 at. %, or as a single phase thin film when Ag volume fraction represents less than 15 at. %. The texture evolution of Cu (111) and Ag (111) in phase-segregated Cu-Ag thin films proves to be synergistically enhanced when compared to pure copper or silver thin films. Not only is a stronger perpendicular (111) fiber texture obtained, but also an in-plane alignment of Ag (200) develops related to deposition direction and composition. By the use of transmission electron microscopy we observed a decrease in grain size in Cu-Ag composite films as compared with pure copper and silver films. These Cu-Ag thin films are being evaluated for antimicrobial applications.