AVS 56th International Symposium & Exhibition
    Surface Science Thursday Sessions
       Session SS-ThP

Paper SS-ThP11
One and Two Dimensional Structures of Water on Cu(110) and O/Cu(110)-(2x1) Surface

Thursday, November 12, 2009, 6:00 pm, Room Hall 3

Session: Surface Science Poster Session
Presenter: Y. Shi, Lawrence Berkeley National Laboratory
Authors: B.Y. Choi, Lawrence Berkeley National Laboratory
Y. Shi, Lawrence Berkeley National Laboratory
M. Salmeron, Lawrence Berkeley National Laboratory
Correspondent: Click to Email

The interaction of water molecules with single crystalline surfaces provides a model for a fundamental understanding of the wetting properties of metals. We investigate one and two dimensional water structures on a clean and on an oxygen precovered Cu(110) surface using scanning tunneling microscopy and non-contact atomic force microscopy. In previous work it has been proposed that at sub-monolayer coverage water forms pentagon based chain-like structure on the clean Cu(110) surface at low temperature. Water pentagons have a strong water-metal interaction as well as a minimal strain in hydrogen bond1. On an oxygen precovered Cu(110) surface, hexagonal based honeycomb structures are preferred to form along the Cu-O stripes. However, it is not clear whether the hexamers are composed of intact or half-dissociated water molecules2. We will discuss how the Cu-O stripes affect the formation of the honeycomb structures and chains of water pentamers.

1J. Carrasco et.al Nature Mater. 8, 427 (2009)

2J. Ren et.al Phys. Rev. B 77, 054110 (2008)