AVS 56th International Symposium & Exhibition
    Advanced Surface Engineering Monday Sessions
       Session SE1-MoM

Paper SE1-MoM5
Effects of Oxygen Vacancies on Electro-Optic Properties of Reactively Co-Sputtered Nb-doped Titania Films

Monday, November 9, 2009, 9:40 am, Room B1

Session: Photocatalytic Coatings
Presenter: M.S. Wong, National Dong Hwa University, Taiwan
Authors: H.C. Hsing, National Dong Hwa University, Taiwan
H.T. Chang, National Dong Hwa University, Taiwan
T.Y. Lu, National Dong Hwa University, Taiwan
C.C. Mo, National Dong Hwa University, Taiwan
M.S. Wong, National Dong Hwa University, Taiwan
Correspondent: Click to Email

Transparent conducting niobium-doped titania was prepared by reactive co-sputtering of Ti and Nb metal targets in oxygen and argon plasma. The as-deposit films were annealed at 650℃ under air atmosphere for 8 hr and then hydrogen annealed. Two different H2-annealig procedures were executed to generate different concentration of oxygen vacancies: the H2-annealing time ranges from 10 min to 4 hr under constant temperature and H2-annealing temperature ranges from 200℃ to 800℃ under constant time. From the XPS spectra, the concentration of oxygen vacancies was observed, and directly affects the carrier concentrations in the thin film. The thin film’s structure and optical properties was also measured and discussed.