AVS 56th International Symposium & Exhibition
    Nanometer-scale Science and Technology Wednesday Sessions
       Session NS-WeM

Paper NS-WeM5
The Role of Surface Chemistry on the Properties of Nanoporous Gold

Wednesday, November 11, 2009, 9:20 am, Room L

Session: Nanoscale Devices and Sensors and Welch Award
Presenter: J. Biener, Lawrence Livermore National Laboratory
Authors: J. Biener, Lawrence Livermore National Laboratory
M.M. Biener, Lawrence Livermore National Laboratory
A.V. Hamza, Lawrence Livermore National Laboratory
A. Wittstock, Universität Bremen, Germany
M. Bäumer, Universität Bremen, Germany
D. Kramer, Forschungszentrum Karlsruhe, Germany
R.N. Viswanath, Forschungszentrum Karlsruhe, Germany
J. Weissmüller, Forschungszentrum Karlsruhe, Germany
Correspondent: Click to Email

Although surfaces or, more precisely, surface atoms determine the way how materials interact with their environment, the influence of surface chemistry on the bulk of the material is generally considered to be small. However, in the case of high surface area materials such as nanoporous gold the influence of surface properties can no longer be neglected. Therefore, actively controlling surface properties such as diffusion barriers and surface stress by surface chemistry should provide an opportunity to manipulate and fine-tune material properties. Specifically, we will show that surface chemistry is an important factor in determining the stability of nanostructured gold surfaces, and that macroscopic strain can be generated by surface-chemistry induced changes of the surface stress. The latter effect can be used to directly convert chemical energy into a mechanical response without generating heat or electricity first and thus opens the door to surface-chemistry driven actuator and sensor technologies.

Prepared by LLNL under Contract DE-AC52-07NA27344.