AVS 56th International Symposium & Exhibition
    Nanometer-scale Science and Technology Tuesday Sessions
       Session NS-TuP

Paper NS-TuP17
Growth and Optical Properties of ZnO Fern-like Nanoleaves

Tuesday, November 10, 2009, 6:00 pm, Room Hall 3

Session: Nanometer-scale Science and Technology Poster Session
Presenter: H. Gao, Harbin Normal University, P.R. China
Authors: H. Ji, Jilin University, P.R. China
H. Gao, Harbin Normal University, P.R. China
Y. Zhao, Northeast Forestry University, P.R. China
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Zinc oxide is a very widely studied nanomaterial due to its potential applications in nanoscale optoelectronic and photovoltaic devices. A variety of ZnO quasi-one-dimensional morphologies have been synthesized by different methods. Often applications of the ZnO nanostructures are closed related to their morphology providing motivation to study the relationship between the morphology and growth technique.

Using a mixture of ZnO, Eu2O3 and C powder as source material, ZnO with a novel morphology referred to as nanoleaves was fabricated using thermal evaporation. The structures and morphologies of the as-synthesized samples were characterized by x-ray diffraction, field-emission scanning electron microscopy, high-resolution transmission electron microscopy and energy dispersive x-ray spectroscopy. The ZnO nanoleaves are wurtzite single crystals that have an appearance of fern-like leaves w ith symmetrical paired teeth on opposite sides. For some of the nanoleaves, there are long needles that grow from the end of some of the teeth and forming parallel arrays. The growth mechanism, kinetically driven process and photoluminescence of the ZnO nanoleaves will be discussed.