AVS 56th International Symposium & Exhibition
    Graphene Topical Conference Tuesday Sessions
       Session GR-TuP

Paper GR-TuP1
Reduction of Graphene Oxide using Electron Beam Generated Plasmas

Tuesday, November 10, 2009, 6:00 pm, Room Hall 3

Session: Graphene Topical Conference Poster Session
Presenter: M. Baraket, Naval Research Laboratory
Authors: M. Baraket, Naval Research Laboratory
E.H. Lock, Naval Research Laboratory
S.G. Walton, Naval Research Laboratory
Correspondent: Click to Email

Graphene and graphene oxide are the subject of intense research because of their unique structural and electronic properties which are advantageous in a large number of applications including nano-electronic and sensing devices. The amount of oxygen present in graphene oxide sheets strongly modifies their properties. Processes aiming to the reduction of oxygen are a current research interest. Wet-chemical approaches have been successful, but these methods have critical drawbacks in terms of scalability and time consumption. Plasma-based processes are an attractive replacement. The electron beam generated plasma developed by the Naval Research Laboratory provides a unique low electron temperature (< 1 eV) plasma and thus any ions leaving the plasma will do so with low ion kinetic energies at substrates. This novel plasma processing technique allows surface modification without excessive etching or surface damage. Experimental investigation of the reactions between plasmas produced in different gases (Ar, CH4 and/or H2 mixtures) and graphene oxide in an effort to reduce the concentration of oxygen will be presented. Material characterizations (chemistry, surface energy and surface roughness) and in-situ plasma diagnostics (electron temperature, plasma density) will also be discussed. This work was supported by the Office of the Naval Research. M.B and E.L. appreciate the support of the National Research Council.