AVS 56th International Symposium & Exhibition
    Applied Surface Science Wednesday Sessions
       Session AS-WeM

Paper AS-WeM11
Formation of Hydroxyapatite Films on Thin Etridonate Films formed on Stainless Steel and Titanium Studied by Core and Valence Band XPS - A Potentially Biocompatible Surface for Implants

Wednesday, November 11, 2009, 11:20 am, Room C2

Session: Electron Spectroscopies
Presenter: P. Sherwood, Oklahoma State University
Authors: F. Gao, Oklahoma State University
P. Sherwood, Oklahoma State University
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This work reports the preparation of hydroxyapatite films formed on metals which were coated with a thin oxide free film of metal etidronate. The metals studied were stainless steel and titanium. The key to adhesion of the hydroxyapatite films is the initial formation of a thin, oxide free, etidronate film on the metal. It was not found possible to prepare the hydroxyapatite films directly on the metal surfaces. Since hydroxyapatite is a key component of bone and teeth, it is likely that the coated metals will have desirable biocompatible properties, and that these treated metals may find applications in the production of medical implants. The surface chemistry of the films was examined by core and valence band X-ray photoelectron spectroscopy. The valence band spectra were interpreted by cluster and band structure calculations. The valence band spectra proved especially valuable in the identification of the surface chemistry of the films.