AVS 55th International Symposium & Exhibition
    Vacuum Technology Monday Sessions
       Session VT-MoA

Paper VT-MoA4
A Sensor for Detecting Extremely Low Concentrations of Heavy Hydrocarbons in Vacuum Systems

Monday, October 20, 2008, 3:00 pm, Room 205

Session: Vacuum Cleanliness, Outgassing, Contamination, and Gas Dynamics
Presenter: N.B. Koster, TNO Science and Industry, The Netherlands
Authors: N.B. Koster, TNO Science and Industry, The Netherlands
R. Jansen, TNO Science and Industry, The Netherlands
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At present vacuum systems are becoming more and more complex and are growing towards a full industrial scale. Together with this growth in size and complexity the cleanliness demands are also becoming more strict. Especially for Extreme Ultra Violet Lithography (EUVL) the requirements on hydrocarbon concentration are high. Typically the total concentration of hydrocarbons in such a tool must be below 1*10-12 mbar integrated over the mass range 45 to 200 in order to maintain the optics quality during lifetime of the EUVL tool. This also means that the requirements for components and sub-assemblies are even more strict and because the tool cannot be baked the cleanliness has to be verified before integration in the tool. These type of cleanliness demands are also becoming more important for other applications like ALD, CVD, fusion and accelerator systems. We present a sensor, that we are currently developing, that is able to measure the total concentration of heavy hydrocarbons (including fluor compounds) from mass 100 up to infinity in a single channel. The sensor is based on a ionisation source in combination with a magnetic analyser that is used as a low mass filter for removing the species that are of no interest. The masses of interest are led towards a single channel detector for readout of the hydrocarbon partial pressure. Unlike an ordinary RGA the mass range is not scanned but aquired on a single detector, which leads to a significantly higher signal. Also, unlike a RGA, the noise level of the detector is not summed over the scanned mass range, but remains constant. As the sensor is a one channel detector it acts as a Mass Filtered Ion Gauge (MFIG) giving a signal for total concentration of heavy molecules. The benefit of such a sensor is that it gives a single output which enables a go / no go decision for vacuum qualification of chambers and components or in-situ monitoring of contamination levels in a tool. We expect that the sensor has a lower detection limit below 1*10-13 mbar when operating in faraday mode. The detection limit can be further increased by adding a Secondary Electron Multiplier (SEM) like a Multi Channel Plate (MCP) in front of the faraday detector. This can increase the sensitivity with a factor 100 to 1000. We will present our first results of the sensor when operating at vacuum levels between 1*10-6 and 1*10-9 mbar.