AVS 55th International Symposium & Exhibition
    Tribology Focus Topic Thursday Sessions
       Session TR-ThP

Paper TR-ThP2
ToF-SIMS Investigations of Tribological Layers

Thursday, October 23, 2008, 6:00 pm, Room Hall D

Session: Tribology Poster Session
Presenter: C. Bruening, University of Muenster, Germany
Authors: C. Bruening, University of Muenster, Germany
D. Lipinsky, University of Muenster, Germany
S. Neudörfer, University of Hannover, Germany
G. Poll, University of Hannover, Germany
H.F. Arlinghaus, University of Muenster, Germany
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The formation of tribofilms plays a critical role in the longevity of automotive gears. A wide variety of anti-wear and extreme-pressure additives are commercially available for oil modification to build tribological layers and to reduce the friction between different friction partners and enhance the stability of the gear unit. Nevertheless, the behaviour of these layers under different stresses is not well understood. For this study, friction experiments under conditions typical for gear synchronisation were performed. Under standardized conditions on a test bench, rotating synchronisation rings fitted with typical friction linings consisting of brass, scatter sinter or carbon were decelerated on stainless steel cones. As lubricant, commercial gear oil was used, containing zinc dialkyldithiophosphate (ZDDP) and calcium sulfonate acting as AW/EP additive or as detergent, respectively. ToF-SIMS with its high surface sensitivity is well suited for these investigations. It was used to characterize the tribofilms generated by the wear process. Differences in contact pressures, relative velocities of the friction partners, and durations of stress led to the generation of different tribofilms, which is indicated by TOF-SIMS spectra, lateral distribution images, and depth profiles.