AVS 55th International Symposium & Exhibition
    Surface Science Thursday Sessions
       Session SS1+NC-ThA

Invited Paper SS1+NC-ThA1
Structure and Kinetics of Nanoscale Amorphous and Crystalline Ice Films on Various Substrates

Thursday, October 23, 2008, 2:00 pm, Room 207

Session: Water-Surface Interactions
Presenter: B.D. Kay, Pacific Northwest National Laboratory
Authors: B.D. Kay, Pacific Northwest National Laboratory
J.L. Daschbach, Pacific Northwest National Laboratory
Z. Dohnálek, Pacific Northwest National Laboratory
G.A. Kimmel, Pacific Northwest National Laboratory
J. Matthiesen, Pacific Northwest National Laboratory
N.G. Petrik, Pacific Northwest National Laboratory
R.S. Smith, Pacific Northwest National Laboratory
T. Zubkov, Pacific Northwest National Laboratory
Correspondent: Click to Email

Molecular beam scattering, programmed desorption (both TPD and isothermal), and vibrational spectroscopy are used to study the chemical kinetics and reaction dynamics of molecular processes occurring both on the surface and within the bulk of amorphous and crystalline ice films. Molecular beams are used to synthesize chemically and structurally tailored thin films on various substrates including Pt(111), Pd(111), C(111) and FeO(111). These films can have morphologies ranging from dense and smooth, to highly porous depending on growth conditions. The precise control of the film structure allows physiochemical processes such as densification, crystallization, diffusion, isotope exchange, solvation, and dewetting to be studied in detail. The experimental methods, results, and their relevance to supercooled water, astrophysical icy bodies, wetting phenomena and nanoporous materials will be presented. Pacific Northwest National Laboratory is a multiprogram national laboratory operated for the U.S. Department of Energy by Battelle Memorial Institute under contract DE-AC06-76RLO 1830.