AVS 54th International Symposium
    Thin Film Tuesday Sessions
       Session TF-TuP

Paper TF-TuP5
Role of Carbon Nanotube and Water in Photoconductivity of Polythiophne Based Water Soluble Polymer

Tuesday, October 16, 2007, 6:00 pm, Room 4C

Session: Aspects of Thin Films Poster Session
Presenter: D.Y. Kim, Wayne State Univ.
Authors: J. Choi, Wayne State Univ.
D.Y. Kim, Wayne State Univ.
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Polythiophene based water soluble polymer, Sodium poly[2-(3-thienyl)-ethoxy-4-butylsulfonate)] (PTEBS) is attractive as a strong candidate for photovoltaic devices and humidity sensor. PTBS is water soluble, processable using conventional solvents, and shows high response to visible light. However, the higher energy band gap and the low conductivity of the polymer are obstacles for the full utilization of full visible light spectrum range and efficient charge separation, which are critical to the efficiency of photovoltaic devices. In order to develop an efficient solar cell, understanding conduction mechanism of polymer is essential. To overcome the obstacles related to the intrinsic properties of PTEBS, we studied the photo-response as a function of voltage, polymer concentration, carbon nanotube, phase and wavelength of light. In result, we found out the photo-response depends on the applied bias voltages, carbon nanotube incorporation, wavelength of light, phase of polymer and humidity. These results can be directly applicable to design efficient photovoltaic devices for the practical applications.