AVS 54th International Symposium
    Surface Science Tuesday Sessions
       Session SS2-TuM

Paper SS2-TuM6
Structure of the Al(100)-c(2x2)Ti Surface*

Tuesday, October 16, 2007, 9:40 am, Room 611

Session: Surface Structure and Growth on Metals
Presenter: M. Kopczyk, Montana State University
Authors: M. Kopczyk, Montana State University
W. Priyantha, Montana State University
H. Chen, Montana State University
D. Tonn, Balwin-Wallace Collage
R.J. Smith, Montana State University
D.S. Choi, Kangwon National University, Korea
G. Bozzolo, Ohio Aerospace Institute
Correspondent: Click to Email

The atomic structure of sub-monolayer amounts of Ti deposited on the Al(100) surface at room temperature has been studied using low-energy electron diffraction (LEED) and low-energy ion-scattering spectroscopy (LEIS/ ISS). The Ti coverage was determined using Rutherford backscattering spectroscopy. From the symmetry of the observed c(2x2) LEED images we infer a structure which places the Ti atoms in every other Al unit cell. Analysis of the LEIS spectra, including both azimuth- and polar-angle scans, corroborates this hypothesis. This conclusion is relevant to recent studies of Ti as a catalyst in Na alinates presently being studied for their use in hydrogen storage applications important in fuel cell research.

*This work was supported by the National Science Foundation, NSF Grant DMR 0516603.