AVS 54th International Symposium
    Magnetic Interfaces and Nanostructures Wednesday Sessions
       Session MI-WeM

Paper MI-WeM6
Induced Spin Polarization of Copper Spin 1/2 Molecular Layers

Wednesday, October 17, 2007, 9:40 am, Room 619

Session: Magnetic Thin Films and Nanostructures
Presenter: D.S. Wisbey, University of Nebraska-Lincoln
Authors: D.S. Wisbey, University of Nebraska-Lincoln
D. Feng, University of Nebraska-Lincoln
A.N. Caruso, North Dakota State University
C.M. Silvernail, University of Minnesota
J. Belot, University of Nebraska-Lincoln
E. Vescovo, National Synchrotron Light Source
P.A. Dowben, University of Nebraska-Lincoln
Correspondent: Click to Email

Substrate induced spin polarization was observed in molecular layers of C24H36N2O4Cu (Cu(CNdpm)2) deposited on cobalt (111). Extra molecular interactions between these Cu 1/2 molecules and the ferromagnetic substrate are implicated while the Cu(CNdpm)2 molecular layers have an opposite spin polarization compared to the Co(111) substrate near the Fermi edge. The spin-polarized photoemission results are seen to be consistent with magnetometry and mean field (Ginzburg-Landau) models. The spin asymmetry favors select molecular orbitals, suggesting that the local spin 1/2 moment of copper is enhanced by contributions from select molecular orbitals.