AVS 54th International Symposium
    Electronic Materials and Processing Tuesday Sessions
       Session EM-TuM

Paper EM-TuM1
Dynamics of Molecular Switch Molecules Imaged by Alternating Current Scanning Tunneling Microscopy

Tuesday, October 16, 2007, 8:00 am, Room 612

Session: Molecular Electronics
Presenter: A.M. Moore, The Pennsylvania State University
Authors: A.M. Moore, The Pennsylvania State University
P.S. Weiss, The Pennsylvania State University
Correspondent: Click to Email

We have studied oligo(phenylene-ethylene) (OPE) molecules as candidates for molecular electronic switches. We previously determined the switching mechanism to rely on hybridization changes between the substrate and molecule. Here, we have determined which molecules will be more or less active in our samples using a custom-built alternating current scanning tunneling microscope (ACSTM). The polarizabilities of the OPE molecules are observed using the ACSTM magnitude signal. The stability of the ACSTM magnitude correlates to the stability of the switches in our samples. From this, we can determine which molecules are more likely to exhibit motion and/or switching events and which molecules will remain stable in our images.