Pacific Rim Symposium on Surfaces, Coatings and Interfaces (PacSurf 2014)
    Energy Harvesting & Storage Tuesday Sessions
       Session EH-TuP

Paper EH-TuP8
Fabrication of Structured Organic Solar Cell with Patterned ITO Electrode and Study of Their Effect on Power Conversion Efficiency

Tuesday, December 9, 2014, 4:00 pm, Room Mauka

Session: Energy Harvesting & Storage Poster Session
Presenter: Jin-Hyo Boo, Sungkyunkwan University, Korea
Authors: J.-H. Boo, Sungkyunkwan University, Korea
J.S. Lee, Sungkyunkwan University, Korea
Correspondent: Click to Email

In organic photovoltaics (OPVs), there is a competition between the reduction of absorber thickness and the improvement of the probability of carrier collection. To overcome the competition a highly structured interface is highly desirable. However, a solution-based soft-lithography processing resulted in non-uniform structured surfaces. In this report, we proposed and demonstrated a silica-templated soft-lithographical approach for structuring well-defined and controllable transparent ITO layer for enhancing power conversion efficiency (PCE). Also, we focused on the morphological effects of the patterned ITO on optical properties and PCE.

The brief experimental scheme is as follow. First, close-packed PS nanospheres were formed on a cleaned ITO glass substrate by using gas-liquid-solid interfacial self-assembly method and drying for 3days in vacuum desiccator. After that, PS covered ITO glass was etched at 65℃ with TIN etching solution. Finally, PEDOT:PSS, P3HT:PCBM, and Al electrode were gradually deposited.

The morphology, optical, electric, and cell properties are investigated by FE-SEM, AFM, UV-VIS spectrophotometer, Haze measurement, and solar simulator.